1z6e

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Revision as of 21:23, 12 November 2007 by OCA (talk | contribs) (New page: left|200px<br /> <applet load="1z6e" size="450" color="white" frame="true" align="right" spinBox="true" caption="1z6e, resolution 1.8Å" /> '''Crystal Structure of...)
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File:1z6e.gif


1z6e, resolution 1.8Å

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Crystal Structure of Factor Xa complexed to Razaxaban

OverviewOverview

Modification of a series of pyrazole factor Xa inhibitors to incorporate, an aminobenzisoxazole as the P(1) ligand resulted in compounds with, improved selectivity for factor Xa relative to trypsin and plasma, kallikrein. Further optimization of the P(4) moiety led to compounds with, enhanced permeability and reduced protein binding. The SAR and, pharmacokinetic profile of this series of compounds is described herein., These efforts culminated in, 1-(3'-aminobenzisoxazol-5'-yl)-3-trifluoromethyl-N-[2-fluoro-4-[(2'-dimeth, ylaminomethyl)imidazol-1-yl]phenyl]-1H-pyrazole-5-carboxyamide (11d), a, potent, selective, and orally bioavailable inhibitor of factor Xa. On the, basis of its excellent in vitro potency and selectivity profile, high free, fraction in human plasma, good oral bioavailability, and in vivo efficacy, in antithrombotic models, the HCl salt of this compound was selected for, clinical development as razaxaban (DPC 906, BMS-561389).

DiseaseDisease

Known disease associated with this structure: Factor X deficiency OMIM:[227600]

About this StructureAbout this Structure

1Z6E is a Protein complex structure of sequences from Homo sapiens with IK8 as ligand. Active as Coagulation factor Xa, with EC number 3.4.21.6 Full crystallographic information is available from OCA.

ReferenceReference

Discovery of 1-(3'-aminobenzisoxazol-5'-yl)-3-trifluoromethyl-N-[2-fluoro-4- [(2'-dimethylaminomethyl)imidazol-1-yl]phenyl]-1H-pyrazole-5-carboxyamide hydrochloride (razaxaban), a highly potent, selective, and orally bioavailable factor Xa inhibitor., Quan ML, Lam PY, Han Q, Pinto DJ, He MY, Li R, Ellis CD, Clark CG, Teleha CA, Sun JH, Alexander RS, Bai S, Luettgen JM, Knabb RM, Wong PC, Wexler RR, J Med Chem. 2005 Mar 24;48(6):1729-44. PMID:15771420

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