SN1 reaction

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Revision as of 15:08, 21 April 2013 by Jaime Prilusky (talk | contribs) (New page: == S<sub>N</sub>1-Substitution of Cl<sup>-</sup> and ''tert''-Butanol == <Structure load='SN1_animation3d.xyz.gz' size='400' frame='true' align='right' caption='' scene='' /> In general, ...)
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SN1-Substitution of Cl- and tert-ButanolSN1-Substitution of Cl- and tert-Butanol

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In general, SN1 substitution can take place when a stable carbocation can be formed. If not, the reaction follows the SN2 mechanism. The SN1 with the removement of a hydroxide-ion out of the molecule, in this case tert-Butanol. By this, a positively charged carbocation with a planar geometry is formed. This step is also the rate-determing step because it is the slowest step in this reaction. In the , the haloanion bound to the carbocation, and a neutral haloalkane is formed. With this step, the hydroxy-substituent is replaced by a halogen-substituent.


This demo was adapted from http://www.chemieunterricht-interaktiv.de/en/animations/sn1_substutition/sn1_substitution_3d.html by Dr. V. Pietzner, part of the ChiLe project

Proteopedia Page Contributors and Editors (what is this?)Proteopedia Page Contributors and Editors (what is this?)

Jaime Prilusky, Verena Pietzner, Angel Herraez, Joel L. Sussman