Photosystem II: Difference between revisions

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==Oxygen Evolution==
==Oxygen Evolution==
Another important facet of photosystem II is its ability to oxidize water to oxygen with its <scene name='Photosystem_II/Oxygen_evolving_centers/1'>oxygen evolving centers</scene>.  These centers were shown to be cubane-like Mn<sub>3 CaO<sub>4 cluster linked to a fourth Mn by a mono-μ-oxo bridge. [1]  
Another important facet of photosystem II is its ability to oxidize water to oxygen with its <scene name='Photosystem_II/Oxygen_evolving_centers/1'>oxygen evolving centers</scene>.  These centers were shown to be cubane-like Mn</sub>3 CaO</sub>4 cluster linked to a fourth Mn by a mono-μ-oxo bridge. [1]  





Revision as of 23:46, 4 May 2008

PDB ID 1s5l

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BackgroundBackground

Photosystem II, crystallized from the bacteria, Thermosynechococcus elongatus, at 3.50 Å, is representative of the photosynthetic protein found in cyanobacteria and plants. The protein is associated with a variety of ligands. It is mainly composed of and is a symmetrical . Fifteen subunits are in each monomer, with multiple subunits associated with the oxygen evolving complex missing from this crystallization. Photosystem II is a membrane bound protein found in the thylakoid membrane of chloroplasts. Analysis of residues orients the protein within the membrane.

PhotosynthesisPhotosynthesis

surround Photosystem II and capture energy from sunlight, exciting electrons. Highly conjugated, these chlorophyll absorb visible light, along with as accessory light harvesting pigments such as that can absorb at other wavelengths.

Chlorophyll_a.svg.png
Chlorophyll_a.svg.png

Beta carotene also protects photosystem II by destroying reactive oxygen species that result from this photoexcitation. b-car.svg.png

Electrons are passed from chlorophyllto . Pheophytin are very similar to chlorophyll except they contain 2 H + instead of a Mg 2+ ion. From the pheophytin, electrons go to , which are reduced. These plastoquinones eventually move to a plastoquinone pool which goes to another large protein subunit, photosystem I, the next step in photosynthesis.


Oxygen EvolutionOxygen Evolution

Another important facet of photosystem II is its ability to oxidize water to oxygen with its . These centers were shown to be cubane-like Mn3 CaO4 cluster linked to a fourth Mn by a mono-μ-oxo bridge. [1]


ReferencesReferences

[1] Ferreira, K.N., Iverson, T.M., Maghlaoui, K., Barber, J., Iwata, S. "Architecture of the photosynthetic oxygen-evolving center." Science, March 19, 2004, 303 (5665), 1831-8.

[2] Garrett, R.H., Grisham, C.M. Biochemistry, 3rd Edition. Belmont, CA: Thomson Brooks/ Cole, 2005.


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