Hexoses: Difference between revisions

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The objective of this article is to illustrate and visualize the structures and concepts related to the structures of glucose (aldohexose<ref>[http://en.wikipedia.org/wiki/Aldohexose Aldohexose]</ref>) and fructose (ketohexose<ref>[http://en.wikipedia.org/wiki/Ketohexose Ketohexose]</ref>).
The objective of this article is to illustrate and visualize the structures and concepts related to the structures of glucose (aldohexose<ref>[http://en.wikipedia.org/wiki/Aldohexose Aldohexose]</ref>) and fructose (ketohexose<ref>[http://en.wikipedia.org/wiki/Ketohexose Ketohexose]</ref>).
[[Image:D-glucose (fischer).png|thumb|left|Figure: Fischer Projection Structure of D-Glucose.]]
[[Image:D-glucose (fischer).png|thumb|left|Figure: Fischer Projection Structure of D-Glucose.]]
The figure to the left contains glucose drawn as a Fischer projection structure. The most oxidized group, in this case the aldehyde group, is is drawn at the top, all horizontal bonds project to the front of the plane of the screen and all vertical bonds are assumed to project behind the plane of the screen.  A structure meeting these characteristics is seen in the scene below.
The figure to the left contains glucose drawn as a Fischer projection structure. The most oxidized group, in this case the aldehyde group, is is drawn at the top, all horizontal bonds project to the front of the plane of the screen and all vertical bonds are assumed to project behind the plane of the screen.  As shown in the scene below if glucose is set in the Fischer projection conformation carbon #6 (green) circles around to meet carbon #1 (orange).


<table width='500' align='right' cellpadding='5'><tr><td rowspan='2'>&nbsp;</td><td bgcolor='#eeeeee'><Structure load='Insert PDB code or filename here' size='490' frame='true' align='right' caption='' scene='Insert optional scene name here' /></td></tr><tr><td bgcolor='#eeeeee'><center>'''Peptide Segments Illustrating Secondary Structures'''<scene name='Ramachandran_Plots/Helix_first/1'> (Initial scene)</scene></center></td></tr></table>
<table width='500' align='right' cellpadding='5'><tr><td rowspan='2'>&nbsp;</td><td bgcolor='#eeeeee'><Structure load='open chain glucose.pdb' size='490' frame='true' align='right' caption='' scene='Hexoses/Glucose_fischer/1' /></td></tr><tr><td bgcolor='#eeeeee'><center>'''Peptide Segments Illustrating Secondary Structures'''<scene name='Hexoses/Glucose_fischer/1'> (Initial scene)</scene></center></td></tr></table>





Revision as of 19:06, 17 October 2011

The objective of this article is to illustrate and visualize the structures and concepts related to the structures of glucose (aldohexose[1]) and fructose (ketohexose[2]).

Figure: Fischer Projection Structure of D-Glucose.

The figure to the left contains glucose drawn as a Fischer projection structure. The most oxidized group, in this case the aldehyde group, is is drawn at the top, all horizontal bonds project to the front of the plane of the screen and all vertical bonds are assumed to project behind the plane of the screen. As shown in the scene below if glucose is set in the Fischer projection conformation carbon #6 (green) circles around to meet carbon #1 (orange).

 
Drag the structure with the mouse to rotate
Peptide Segments Illustrating Secondary Structures


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Karl Oberholser, Alexander Berchansky, Karsten Theis